void registerExtension(String method, ServiceExtensionHandler handler(String method, Map<String, String> parameters))

Register a ServiceExtensionHandler that will be invoked in this isolate for method. NOTE: Service protocol extensions must be registered in each isolate.

NOTE: method must begin with 'ext.' and you should use the following structure to avoid conflicts with other packages: 'ext.package.command'. That is, immediately following the 'ext.' prefix, should be the registering package name followed by another period ('.') and then the command name. For example: 'ext.dart.io.getOpenFiles'.

Because service extensions are isolate specific, clients using extensions must always include an 'isolateId' parameter with each RPC.

Source 

void registerExtension(String method, ServiceExtensionHandler handler) {
  if (method is! String) {
    throw new ArgumentError.value(method,
                                  'method',
                                  'Must be a String');
  }
  if (!method.startsWith('ext.')) {
    throw new ArgumentError.value(method,
                                  'method',
                                  'Must begin with ext.');
  }
  if (_lookupExtension(method) != null) {
    throw new ArgumentError('Extension already registered: $method');
  }
  if (handler is! ServiceExtensionHandler) {
    throw new ArgumentError.value(handler,
                                  'handler',
                                  'Must be a ServiceExtensionHandler');
  }
  _registerExtension(method, handler);
}